This elusive mineral acts as a high-temperature thermometer for cooling volcanic magma

This elusive mineral acts as a high-temperature thermometer for cooling volcanic magma
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In short: Pigeonite is a rare, fleeting mineral that reveals the thermal history of igneous rocks. Because it only remains stable at high temperatures, its presence in volcanic stone serves as a geological thermometer, offering clues about the cooling process and water content of the magma from which it originally crystallized.

Pigeonite belongs to the clinopyroxene subgroup of the pyroxene family, characterized by a chemical formula of (Ca,Mg,Fe)(Mg,Fe)Si2O6. First described in 1900 at its namesake type locality, Pigeon Point on the shores of Lake Superior, this mineral is notoriously difficult to identify. It typically appears as small grains within various rocks, including basalts, andesites, dacites, and gabbros, often occurring alongside augite and plagioclase feldspar.

The mineral's existence is a race against cooling. Pigeonite crystallizes in a monoclinic system, but it is inherently unstable at lower temperatures, where it tends to break down into a combination of augite and orthopyroxene. The specific temperature at which this transition occurs is dictated by the mineral's iron-to-magnesium ratio. For a ratio of approximately 1, the stability limit sits at about 900 °C. Because of this sensitivity, pigeonite is rarely found in slowly cooled intrusive rocks; the slow cooling process allows calcium to migrate out of the structure, forming exsolution lamellae of calcic clinopyroxene and effectively erasing the original pigeonite.

Because it is so easily destroyed by slow cooling, finding pigeonite in volcanic rocks provides a vital window into the crystallization temperature of magma. This, in turn, allows geologists to infer the water content of the original melt. While it is a scarce find on Earth, pigeonite is not restricted to our planet. It has been identified as crystals within meteorites originating from both Mars and the Moon, serving as a silent witness to the volcanic processes occurring on other celestial bodies. Whether found in terrestrial volcanic phenocrysts or extraterrestrial samples, pigeonite remains a sophisticated indicator of the intense heat and rapid cooling required for its survival.

In some instances, such as in the hornfels of the Ironwood iron formation in Ashland County, Wisconsin, pigeonite persists in association with minerals like fayalite, ferroaugite, and magnetite. These occurrences underscore the complexity of mineral formation in contact zones. Despite its name and its initial discovery in Minnesota, the mineral is likely more widespread than current geological records suggest, provided one knows how to look for the subtle textural evidence of its breakdown.

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