Why water behaves so strangely compared to other common substances

Properties of Water · 6:51 · Video: Amoeba Sisters · Watch at the source

In short: Water is everywhere, yet its physical properties are remarkably atypical. From its unusual density to its ability to act as both an acid and a base, the secret to its strange behavior lies in the powerful, invisible bonds holding its molecules together.

The peculiar nature of water stems from extensive hydrogen bonding interactions. Even with a small molar mass of 18.0151 g/mol, water displays remarkably high surface tension, viscosity, entropy of vaporization, and heat of vaporization. These properties are fundamental to how water functions in our environment. This molecular cohesion is reflected in its specific physical measurements, such as a surface tension of 71.97 dynes per centimeter at 25 °C and a viscosity of 0.8903 centipoise.

One of the most striking anomalies is how water behaves when it freezes. Unlike many common substances, solid ice is less dense than liquid water. This occurs because the formation of an open structure in ice allows for maximum hydrogen bonding, a mechanism that differentiates it from the liquid state. This unique density relationship is why water reaches its maximum density of 1.0000 grams per cubic centimetre at 3.98 °C.

Water acts as an amphoteric substance, capable of serving as a base (accepting protons) or an acid (donating protons). This is evident in the autoionization of water, where molecules react to produce hydronium ions (H3O+) and hydroxide ions (OH-). At 25 °C, the concentration of both ions is exactly 1.0 × 10−7 M, maintaining a constant product of 1.0 × 10−14. This process, known as autoionization, involves the liquid state of H2O molecules reacting with one another to reach an equilibrium condition.

This equilibrium is vital for determining acidity. When an acid is introduced, the concentration of H+ ions increases beyond 1.0 × 10−7 M. To maintain the chemical balance, the OH- concentration must decrease, resulting in a solution where [H+] > [OH-], a state we define as acidic using the pH scale. The acidity is calculated using a base-10 logarithm of the hydrogen ion concentration, a value represented by the pH scale.

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